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GNT Thumbnail Alt 3 2015-page-001Advancements in nanotechnology could fundamentally change global approaches to manufacturing, medicine, healthcare, and the environment.

 

In this lecture Dr. Eric Drexler, Senior Visiting Fellow, Oxford Martin School, will look at current advances in the field of advanced nanotechnology, and the impacts and potential applications of their widespread implementation, and Dr. Sonia Trigueros, Co-Director of the Oxford Martin Programme on Nanotechnology, and Oxford Martin Senior Fellow, will consider how targeted nanomedicine could change how we treat disease in the future.

Published on Jan 28, 2016

 

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NSF supports national efforts to bolster water security and supply.
Credit and Larger Version

Today, at the White House Water Summit, the National Science Foundation (NSF) joins other federal agencies to emphasize its commitment to a sustainable water future.March 22, 2016

Access to affordable clean water is vital for energy generation, food cultivation and basic life support. With drought pressure and population demands, water is an increasingly precious resource.

The California drought and Flint water emergency show some of the consequences of clean water shortages. Low-cost, low-energy technologies for both water quality testing and water treatment must be developed to overcome economic barriers and secure America’s future.

1-california-drought-farms

NSF supports national efforts to bolster water security and supply by investing in fundamental science and engineering research.

“Routine and reliable access to safe drinking water is one of the greatest achievements in human history, thanks to science and engineering research,” said Pramod Khargonekar, NSF assistant director for Engineering. “To ensure this accessibility continues, contributions from all research areas — from engineering and physical sciences to the biological and social sciences — are essential. As such, NSF is uniquely positioned to advance water innovations.”

For decades, NSF has funded researchers across disciplines to investigate fundamental water questions and propose novel solutions to challenges.

Despite the importance of water to life on Earth, major gaps exist in our understanding of water availability, quality and dynamics, as well as the impact of human activity and a changing climate on the water system. These gaps must be filled in order to create new concepts for water desalination, purification, reuse and treatments.

Water report60_l“To take on the most urgent challenge facing the world today, NSF and our partner agencies are funding researchers to explore interactions between the water system and land-use changes, the built environment, ecosystem functions and services, and climate change through place-based research and integrative models,” said Roger Wakimoto, NSF assistant director for Geosciences. “Through these activities, we are enabling a new interdisciplinary paradigm in water research.”

NSF-funded demonstrations at today’s White House event:

  • An interactive augmented reality sandbox exhibit to help teach the public about watersheds, lake sciences, and environmental stewardship.
    • The project, led by NSF-funded researcher Louise H. Kellogg, is a collaboration between university scientists and pubic science centers. Partners include University of California, the Davis W. M. Keck Center for Active Visualization in Earth Sciences, the Tahoe Environmental Research Center, the Lawrence Hall of Science, ECHO Lake Aquarium & Science Center, and Audience Viewpoints.
  • A novel technology that uses sound waves to isolate and remove particles from fluids.
    • Jason Dionne of FloDesign Sonics Inc. is supported by the NSF Small Business Innovation Research program to commercialize the technology, which offers a potentially more efficient and environmentally benign method to purify water.
  • The launch of two “smart markets” for water leasing in the country: for groundwater trading in western Nebraska, and for surface-water trading in central Washington State.
    • Mammoth Trading is creating smart markets to automate the process of checking complex regulatory rules for trading and to generate the highest economic gains among participants. By monetizing the value of conserved water, water leases generate a potential new revenue for water users and reward innovation in water use at the farm level. Mammoth Trading’s markets will be available in over 500,000 acres of irrigated farmland. Mammoth Trading grew out of NSF-funded research, which was commercialized through the NSF Innovation Corps (I-Corps™) program.
  • A book series and curriculum to teach children about the water cycle.
    • NSF supports 25 Long-term Ecological Research (LTER) projects across the country and in Antarctica to study ecological processes. The LTER network enables these sites to serve as local and regional “schoolyards” to promote understanding of environmental processes among K-12 students. One outreach tool they employ is the LTER Schoolyard Series, which includes hands-on activity guides and integrates with federal and state science standards.

New NSF investments announced today:

  • $20 million to support cutting-edge water-research projects through the NSF Experimental Program to Stimulate Competitive Research program.
    • Research teams will apply a systems-based, highly integrated approach to determine when and where the impacts of extreme events cascade through the combined social-ecological system. An integrated model of the watershed will be used to test management scenarios and identify strategies for maintaining infrastructure, environmental health and drinking water quality in the face of extreme weather events.
  • $2 million to educate technicians for high-technology fields that drive our nation’s economythrough the NSF Advanced Technology Educationprogram.
    • A project to enhance marine and environmental science education at the five minority-serving community colleges of the Pacific Islands.
      • American Samoa Community College, the College of Micronesia — FSM, the College of the Marshall Islands, Northern Marianas College and Palau Community College will receive support for curriculum development, faculty professional development, internships and field experiences for students, and strengthened scientific infrastructure. Robert Richmond of University of Hawaii, Honolulu is the award’s primary investigator.
    • A college course to increase student engagement and learning around the Hoosick Falls water crisis.
      • The Village of Hoosick Falls in New York recently discovered unsafe concentrations of perfluorooctanoic acid in its public water system. With NSF support, an interdisciplinary group of scientists led byDavid Bond of Bennington College will develop a course to train students in the effective use of science and technology related to water safety.
  • Two workshops planned on new water technologies and systems to give new meaning to the word “wastewater.”
    • Wastewater treatment plants are not only vital to the protection of human health and the environment, but also present opportunities to recover energy and other valuable resources — creating a world-class water infrastructure while reducing the costs to run it. Recognizing this, NSF, the Department of Energy, the Environmental Protection Agency, and the U.S. Department of Agriculture, with the Water Environment Research Foundation, are developing a National Water Resource Recovery Test Bed Facility network and directory to connect researchers, new technology providers and other innovators in the water-resource recovery industry with test facilities appropriate for their needs. NSF is planning two workshops, in May and June 2016, to support the development of appropriate metrics and structure possibilities for the network.
  • A new Nanotechnology Signature Initiative on water sustainability through nanotechnology.
    • Federal agencies participating in the National Nanotechnology Initiative will support a new initiative to focus on applying the unique properties of materials that occur at the nanoscale to increase water availability, improve water delivery and use efficiency, and enable next-generation water-monitoring systems. Participating agencies include the Department of Energy, the Environmental Protection Agency, NASA, the National Institute of Standards and Technology, NSF and the Department of Agriculture.
  •  A new video series to broaden awareness.
    • The series will build on the popular 2013Sustainability: Water episodes to explore how cutting-edge science and engineering research can transform how the country understands, designs and uses water resources and technologies. The videos will be produced by NBC Learn, the educational arm of NBCUniversal News Group, and will be shared in classrooms and with the public across a variety of platforms in the fall of 2016. The four-part series will promote public awareness of:
      • Water resources, the variability of these resources, and water infrastructure designs and needs.
      • Water conservation in rural and urban settings.
      • Water treatment, including purification and desalination techniques.
      • Water quality issues, including salinization and control.
  • Innovative solutions from community college students at the nexus of food-water-energy.
    • NSF and the American Association of Community Colleges have chosen 10 finalists in the second annual Community College Innovation Challenge, which calls on students enrolled in community colleges to propose innovative science, technology, engineering and mathematics (STEM)-based solutions to perplexing, real-world problems.

Significant ongoing NSF investments:

  • Engineering Research Centers for responsible water use.
    • The Engineering Research Center for Re-inventing the Nation’s Urban Water Infrastructure(ReNUWIt), a research partnership among University of California, Berkeley, Colorado School of Mines, New Mexico State University and Stanford University, is facilitating the improvement of the nation’s existing urban water systems through the development of innovative water technologies, management tools and systems-level analysis. This year, ReNUWIt will help advance urban water governance by releasing a set of decision-support tools that will allow utilities to quantify regional urban water resiliency and sustainability; promote the diversification of urban water supply portfolios by enabling virtual trading in regions with shared water resources; and support integrated management of water reuse and stormwater recharge systems.
    • The Nanosystems Engineering Research Center for Nanotechnology Enabled Water Treatment Systems(NEWT), led by Rice University in partnership with Arizona State University, the University of Texas at El Paso and Yale University, is enabling off-grid drinking water. The NEWT Nanosystems ERC is pursuing high-performance and easy-to-deploy water treatment systems that can turn both wastewater and seawater into clean drinking water. The modular treatment systems, which will need less energy and fewer chemicals, will safely enlist the selective properties of reusable engineered nanomaterials to provide clean water at any location or scale.
  • Ongoing grants to study the food-energy-water nexus.
    • NSF has funded 17 grants, totaling $1.2 million, to support workshops on the interactions of food, energy and water, or FEW. Additionally, $6.4 million will supplement existing grants, enabling scientists to conduct additional research.
  • Ongoing grants to study water sustainability and climate.
    • NSF and the U.S. Department of Agriculture’s National Institute for Food and Agriculture have made three sets of awards, the latest totaling $25 million, in the joint Water Sustainability and Climate program. The funding fosters research on how Earth’s water system is linked with climate change, land use and ecosystems.
  • Special report on clean water technologies.
    • Beyond the White House, NSF-funded clean water-related research activities are happening now across the country. Engineers improve lives every day by imagining and creating innovative new technologies and tools. Today, NSF launches a new special report on future engineering solutions for clean water: NSF.gov/water.

Watch the White House Water Summit live atWhiteHouse.gov/live.

Join the conversation online with the hashtag#WHWaterSummit.

-NSF-

Program Contacts

JoAnn Slama Lighty, NSF, (703) 292-5382, jlighty@nsf.gov
Thomas Torgersen, NSF, (703) 292-8549, ttorgers@nsf.gov

Related Websites
Sustainability: Water: https://www.nbclearn.com/sustainability-water
NSF special report: Cleaner water, clearer future:http://www.nsf.gov/water
New grants foster research on food, energy and water: a linked system: http://www.nsf.gov/news/news_summ.jsp?cntn_id=135642
NSF and NIFA award $25 million in grants for study of water sustainability and climate:http://www.nsf.gov/news/news_summ.jsp?cntn_id=132501
On World Water Day, scientists peer into rivers to answer water availability questions:http://www.nsf.gov/discoveries/disc_summ.jsp?cntn_id=137901

Drop of Water 160322080534_1_540x360

Fuel cell electric vehicles have a long way to go before they can compete with their battery EV cousins, and energy storage is a key sticking point when the fuel is hydrogen. Hydrogen is light, plentiful, and fabulously energy dense, but energy storage in a personal mobility unit racing down a crowded highway is a different kind of chicken. Safety, cost, and performance are critical sticking points, and a research team at Lawrence Berkeley Laboratory is on to a solution for at least one of those.

hydrogen energy storage with graphene

Energy Storage Challenges For Hydrogen Fuel Cell EVs

The US Energy Department’s 2015 annual report provides a birds-eye view of the array of energy storage solutions that are emerging for hydrogen fuel cells, including advancements in hydrogen tank technology as well as solids-based storage.

Despite the progress, according to the Energy Department, challenges still remain for stationary and portable fuel cells in terms of raising the energy storage density, and there are “significant challenges” for fuel cell EVs. The problem is this:

Hydrogen has the highest energy per mass of any fuel; however, its low ambient temperature density results in a low energy per unit volume, therefore requiring the development of advanced storage methods that have potential for higher energy density.

The Energy Department has set a goal of 2020 for achieving verifiable hydrogen storage systems for light duty fuel cell EVs that meet the driving public’s thirst for range, comfort, refueling convenience, and performance. Here are the targets:

1.8 kWh/kg system (5.5 wt.% hydrogen)

1.3 kWh/L system (0.040 kg hydrogen/L)

$10/kWh ($333/kg stored hydrogen capacity)

Fuel cell EVs are already leaking into the transportation scene, particularly in California, Japan, and the European Union, notably including Wales.

However, the Energy Department is already looking beyond the current state of on-road technology to meet its 2020 goal. According to the agency, the 300-mile range is being met by using compressed gas, high pressure energy storage technology, and the problem is that competing technology on the market today — primarily gasmobiles and hybrids — already exceeds that range.

To compete for consumers on the open market, the agency is pursuing a near-term goal of improving compressed gas storage, primarily by deploying fiber reinforced composites that enable 700 bar pressure.

The long term goal consists of two pathways. One is to improve “cold” compressed gas energy storage technology, and the other is to go a different route altogether and store hydrogen within materials such as sorbents, chemical hydrogen storage materials, and metal hydrides.

The Berkeley Lab Energy Storage Solution

Where were we? Oh right, Berkeley Lab. Berkeley Lab has been tackling the metal hydride pathway.

Metal hydrides are compounds that consist of a transition metal bonded to hydrogen. They are believed to be the most “technologically relevant” class of materials for storing hydrogen, partly due to the broad range of applications.

That’s the theory. The problem is that when it comes to real world performance, metal hydrides are highly sensitive to contamination and they degrade somewhat rapidly unless properly shielded.

The Berkeley Lab energy storage solution consists of a graphene “filter” encasing nanocrystals of magnesium. With the addition of the graphene layer, the magnesium crystals act as a sort of sponge for absorbing hydrogen, providing both safety and compactness without causing performance issues:

The graphene shields the nanocrystals from oxygen and moisture and contaminants, while tiny, natural holes allow the smaller hydrogen molecules to pass through. This filtering process overcomes common problems degrading the performance of metal hydrides for hydrogen storage.

Berkeley Lab has provided this photo to show off how stable the crystals are when exposed to air (for scale, the bottle cap is about the size of a thumbnail):

graphene hydrogen energy storage

At one atom thick (yes, one atom), graphene is known to be an incredibly finicky material to work with. It is extremely difficult to synthesize it without defects, but that’s not a problem for this energy storage solution. The defects are actually desirable in this case. The tiny gaps enable molecules of hydrogen gas to wriggle through, but oxygen, water, and other contaminants are too large to penetrate the shield.

The new energy formula also solves another key challenge for metal hydrides. They tend to take in and dispense hydrogen at a relatively slow pace, but the Berkeley Lab solution has sped up the intake-outflow cycle significantly. That effect is attributed to the nanoscale size of the graphene-shielded crystals, which provide a greater surface area.

Energy Department Gets The Last Word?

We’ve been having a lively debate about fuel cell electric EVs over here at CleanTechnica, so let’s hear from the Berkeley Lab team:

A potential advantage for hydrogen-fuel-cell vehicles, in addition to their reduced environmental impact over standard-fuel vehicles, is the high specific energy of hydrogen, which means that hydrogen fuel cells can potentially take up less weight than other battery systems and fuel sources while yielding more electrical energy.

However, the team also makes it clear that:

More R&D is needed to realize higher-capacity hydrogen storage for long-range vehicle applications that exceed the performance of existing electric-vehicle batteries…

Among other issues, the next step for a sustainable fuel cell EV future is to develop sustainable and renewable sources for hydrogen fuel. Currently the main source of hydrogen is natural gas, which puts fuel cell EVs in the same boat as battery EVs that draw electricity from a coal or natural gas-fired grid.

Grafoid aa-1-grafoid

 

Kingston, Ontario’s Grafoid Inc. has signed a Memorandum of Understanding (MOU) for the establishment of a strategic joint venture partnership with China’s largest producer and exporter of tungsten products, Xiamen Tungsten Co. Ltd., which will see Xiamen take up to a 20% equity stake in privately held Grafoid, pending the completion of due diligence which is set to conclude on May 22, 2016.

Xiamen’s equity position in Grafoid was negotiated through its parent company, Ottawa’s Focus Graphite Inc. (TSX VENTURE:FMS) (OTCQX:FCSMF) (FRANKFURT:FKC), through the purchase of up to 7 million Grafoid common shares currently held by Focus Graphite.

“In addition to providing Grafoid with a strategic partner, Grafoid’s MOU with Xiamen, has benefits for Focus Graphite. When finalized, it will provide additional funding to allow us to advance our overall mine and transformation plant financing, and potentially open the China market to Focus Graphite for additional offtake partners and the sale of value added graphite products,” said Focus Graphite CEO and Director Gary Economo.

“Specifically, this injection of funding could enable Focus Graphite to advance our Lac Knife detailed engineering and finalize the environmental permitting process” said Economo. “And, it enables us to move to the next stage in assembling our mine CAPEX financing.”

Last September, Grafoid and Focus Graphite finalized two offtake agreements for obtaining graphite concentrate from a mining project at Lac Knife in Quebec for the next 10 years, one of the priorities of the Quebec government’s Plan Nord initiative.
Focus Graphite, with 7.9 million shares, is currently Grafoid’s largest stakeholder.

The MOU will also see the establishment of Xiamen’s business office at the Grafoid Global Technology Center in Kingston, providing Xiamen with a North American base for future business expansion, as well as the establishment of a Grafoid business office in China.

Grafoid’s path to commercialization lies in its patented product, a high-quality graphene trading under the name Mesograf.

Other terms of the MOU include the desire of Xiamen to introduce a clean energy technology platform and associated technologies to the Chinese market, and the opportunity for Grafoid to bring its suite of Mesograf and Amphioxide graphene based products to China.

With the Lac Knife project moving forward, Grafoid is well positioned to supply global markets with with high purity, value-added, cost-competitive graphite products while supporting the next generation battery development platform of Grafoid, Focus Graphite, Stria Lithium Inc., and Braille Battery Inc.

With annual revenue surpassing 10.143B CNY ($1.55B US), Xiamen, a publicly traded company listed on the Shanghai Exchange (SHA:600549), is a major player in that country’s smelting, processing and exporting of tungsten and other non-ferrous metal products, the operation of rare earth business interests, and the supply of battery materials.

Grafoid currently has 17 joint partnership ventures with industrial and academic partners, including Japan’s Mitsui & Co., Hydro Quebec, Rutgers University, the University of Waterloo, and Phos Solar Systems in Greece.

Last February, Grafoid received an $8.1 million investment from the SD Tech Fund of Sustainable Development Technology Canada (SDTC) to help automate the production of Mesograf and end-product development.

Earlier this month, Professor Aiping Yu of the University of Waterloo’s Chemical Engineering department received a $450,000 Strategic Partnership Grant through the Natural Sciences and Engineering Research Council of Canada (NSERC) to help Grafoid develop an advanced graphene fiber based wearable supercapacitor

No More nomorewashin
Cotton textile covered with nanostructures invisible to the naked eye. Image magnified 200 times. Credit: RMIT University

A spot of sunshine is all it could take to get your washing done, thanks to pioneering nano research into self-cleaning textiles.

Researchers at RMIT University in Melbourne, Australia, have developed a cheap and efficient new way to grow special —which can degrade organic matter when exposed to light—directly onto .

The work paves the way towards nano-enhanced textiles that can spontaneously clean themselves of stains and grime simply by being put under a light bulb or worn out in the sun.

Dr Rajesh Ramanathan said the process developed by the team had a variety of applications for catalysis-based industries such as agrochemicals, pharmaceuticals and natural products, and could be easily scaled up to industrial levels.

“The advantage of textiles is they already have a 3D structure so they are great at absorbing light, which in turn speeds up the process of degrading organic matter,” he said.

“There’s more work to do to before we can start throwing out our washing machines, but this advance lays a strong foundation for the future development of fully self-cleaning textiles.”

The researchers from the Ian Potter NanoBioSensing Facility and NanoBiotechnology Research Lab at RMIT worked with copper and silver-based nanostructures, which are known for their ability to absorb visible light.

No more washing: Nano-enhanced textiles clean themselves with light
The red color indicates the presence of silver nanoparticles — the total coverage on the image shows the nanostructures grown by the RMIT team are present throughout the textile. Image magnified 200 times. Credit: RMIT University

When the nanostructures are exposed to light, they receive an energy boost that creates ““. These “hot electrons” release a burst of energy that enables the nanostructures to degrade organic matter.

The challenge for researchers has been to bring the concept out of the lab by working out how to build these nanostructures on an industrial scale and permanently attach them to textiles.

The RMIT team’s novel approach was to grow the nanostructures directly onto the textiles by dipping them into a few solutions, resulting in the development of stable nanostructures within 30 minutes.

No more washing: Nano-enhanced textiles clean themselves with light
Close-up of the nanostructures grown on cotton textiles by RMIT University researchers. Image magnified 150,000 times. Credit: RMIT University

When exposed to , it took less than six minutes for some of the nano-enhanced textiles to spontaneously clean themselves.

“Our next step will be to test our nano-enhanced textiles with organic compounds that could be more relevant to consumers, to see how quickly they can handle common stains like tomato sauce or wine,” Ramanathan said.

The research is published on March 23, 2016 in the high-impact journal Advanced Materials Interfaces.

Explore further: Silver in the washing machine: Nanocoatings release almost no nanoparticles

More information: Samuel R. Anderson et al. Robust Nanostructured Silver and Copper Fabrics with Localized Surface Plasmon Resonance Property for Effective Visible Light Induced Reductive Catalysis, Advanced Materials Interfaces (2016). DOI: 10.1002/admi.201500632

Drop of Water 160322080534_1_540x360
Drop of water. “Hydrogen production through an electrochemical process is at the heart of key renewable energy technologies including water splitting and hydrogen fuel cells,” says Professor Yao.
Credit: © Deyan Georgiev / Fotolia

Groundbreaking research at Griffith University is leading the way in clean energy, with the use of carbon as a way to deliver energy using hydrogen.

Professor Xiangdong Yao and his team from Griffith’s Queensland Micro- and Nanotechnology Centre have successfully managed to use the element to produce hydrogen from water as a replacement for the much more costly platinum.

“Hydrogen production through an electrochemical process is at the heart of key renewable energy technologies including water splitting and hydrogen fuel cells,” says Professor Yao.

“Despite tremendous efforts, exploring cheap, efficient and durable electrocatalysts for hydrogen evolution still remains a great challenge.

“Platinum is the most active and stable electrocatalyst for this purpose, however its low abundance and consequent high cost severely limits its large-scale commercial applications.

“We have now developed this carbon-based catalyst, which only contains a very small amount of nickel and can completely replace the platinum for efficient and cost-effective hydrogen production from water.

“In our research, we synthesize a nickel-carbon-based catalyst, from carbonization of metal-organic frameworks, to replace currently best-known platinum-based materials for electrocatalytic hydrogen evolution.

“This nickel-carbon-based catalyst can be activated to obtain isolated nickel atoms on the graphitic carbon support when applying electrochemical potential, exhibiting highly efficient hydrogen evolution performance and impressive durability.”

Proponents of a hydrogen economy advocate hydrogen as a potential fuel for motive power including cars and boats and on-board auxiliary power, stationary power generation (e.g., for the energy needs of buildings), and as an energy storage medium (e.g., for interconversion from excess electric power generated off-peak).

Professor Yao says that this work may enable new opportunities for designing and tuning properties of electrocatalysts at atomic scale for large-scale water electrolysis.


Story Source:

The above post is reprinted from materials provided by Griffith University. Note: Materials may be edited for content and length.


Journal Reference:

  1. Lili Fan, Peng Fei Liu, Xuecheng Yan, Lin Gu, Zhen Zhong Yang, Hua Gui Yang, Shilun Qiu, Xiangdong Yao.Atomically isolated nickel species anchored on graphitized carbon for efficient hydrogen evolution electrocatalysis. Nature Communications, 2016; 7: 10667 DOI: 10.1038/ncomms10667

Deposit Naon parts printingnanoPrinting has come a long way since the days of Johannes Gutenberg. Now, researchers have developed a new method that uses plasma to print nanomaterials onto a 3-D object or flexible surface, such as paper or cloth. The technique could make it easier and cheaper to build devices like wearable chemical and biological sensors, flexible memory devices and batteries, and integrated circuits.

One of the most common methods to deposit nanomaterials—such as a layer of nanoparticles or nanotubes—onto a surface is with an inkjet printer similar to an ordinary printer found in an office. Although they use well-established technology and are relatively cheap, have limitations. They can’t print on textiles or other flexible materials, let alone 3-D objects. They also must print liquid ink, and not all materials are easily made into a liquid.

Some nanomaterials can be printed using aerosol printing techniques. But the material must be heated several hundreds of degrees to consolidate into a thin and smooth film. The extra step is impossible for printing on cloth or other materials that can burn, and means higher cost for the materials that can take the heat.

Deposit Naon parts printingnano
The nozzle firing a jet of carbon nanotubes with helium plasma off and on. When the plasma is off, the density of carbon nanotubes is small. The plasma focuses the nanotubes onto the substrate with high density and good adhesion. Credit: …more

The plasma method skips this heating step and works at temperatures not much warmer than 40 degrees Celsius. “You can use it to deposit things on paper, plastic, cotton, or any kind of textile,” said Meyya Meyyappan of NASA Ames Research Center. “It’s ideal for soft substrates.” It also doesn’t require the printing material to be liquid.

The researchers, from NASA Ames and Stanford Linear Accelerator Center, describe their work in the American Institute of Physics journal Applied Physics Letters.

They demonstrated their technique by printing a layer of carbon nanotubes on paper. They mixed the nanotubes into a plasma of helium ions, which they then blasted through a nozzle and onto paper. The plasma focuses the nanoparticles onto the paper surface, forming a consolidated layer without any need for additional heating.

The team printed two simple chemical and . The presence of certain molecules can change the electrical resistance of the carbon nanotubes. By measuring this change, the device can identify and determine the concentration of the molecule. The researchers made a chemical sensor that detects ammonia gas and a biological sensor that detects dopamine, a molecule linked to disorders like Parkinson’s disease and epilepsy.

But these were just simple proofs-of-principle, Meyyappan said. “There’s a wide range of biosensing applications.” For example, you can make sensors that monitor health biomarkers like cholesterol, or food-borne pathogens like E. coli and Salmonella.

Because the method uses a simple nozzle, it’s versatile and can be easily scaled up. For example, a system could have many nozzles like a showerhead, allowing it to print on large areas. Or, the nozzle could act like a hose, free to spray nanomaterials on the surfaces of 3-D objects.

“It can do things inkjet printing cannot do,” Meyyappan said. “But anything inkjet printing can do, it can be pretty competitive.”

The method is ready for commercialization, Meyyappan said, and should be relatively inexpensive and straightforward to develop. Right now, the researchers are designing the technique to print other kinds of materials such as copper. They can then print materials used for batteries onto thin sheets of metal such as aluminum. The sheet can then be rolled into tiny batteries for cellphones or other devices.

Explore further: Ink with tin nanoparticles could print future circuit boards

More information: “Plasma jet printing for flexible substrates,” R. Gandhiraman, E. Singh, D. Diaz-Cartagena, D. Nordlund, J. Koehne and M. Meyyappan,Applied Physics Letters , March 22, 2016. DOI: 10.1063/1.4943792

GH Gas 031716 global-climate-changeHybrid materials developed at Berkeley Lab could lead to cheaper ways to reduce power plant greenhouse gas emissions

In this animation, exhaust from a power plant contacts a hybrid membrane recently developed at Berkeley Lab. The membrane’s carbon dioxide highways (yellow) enable the rapid flow of carbon dioxide (red and white molecules) while maintaining selectivity over nitrogen (blue molecules). The membrane is eight times more carbon dioxide permeable than a polymer-only membrane. (Credit: Berkeley Lab)

A new, highly permeable carbon capture membrane developed by scientists from the U.S. Department of Energy’s Lawrence Berkeley National Laboratory (Berkeley Lab) could lead to more efficient ways of separating carbon dioxide from power plant exhaust, preventing the greenhouse gas from entering the atmosphere and contributing to climate change.

The researchers focused on a hybrid membrane that is part polymer and part metal-organic framework, which is a porous three-dimensional crystal with a large internal surface area that can absorb enormous quantities of molecules.

In a first, the scientists engineered the membrane so that carbon dioxide molecules can travel through it via two distinct channels. Molecules can travel through the polymer component of the membrane, like they do in conventional gas-separation membranes. Or molecules can flow through “carbon dioxide highways” created by adjacent metal-organic frameworks.

Initial tests show this two-route approach makes the hybrid membrane eight times more carbon dioxide permeable than membranes composed only of the polymer. Boosting carbon dioxide permeability is a big goal in efforts to develop carbon capture materials that are energy efficient and cost competitive.

The research is the cover article of the March issue of the journalEnergy & Environmental Science.

“In our membrane, some CO2 molecules get an express ride through the highways formed by metal-organic frameworks, while others take the polymer pathway. This new approach will enable the design of higher performing gas separation membranes,” says Norman Su, a graduate student in the Chemical and Biomolecular Engineering Department at UC Berkeley and a user at the Molecular Foundry.

He conducted the research with Jeff Urban, Facility Director of the Inorganic Nanostructures Facility at the Molecular Foundry, and a team of scientists that included staff at the Advanced Light Source.

Capturing carbon emissions from electric power plants and other sources is a hot research topic because there’s a lot of room for improvement. The conventional way of separating carbon dioxide from flue gas is amine adsorption, which isn’t economical at scale because it adds significant capital cost and reduces the electrical output of power plants.

Scientists are exploring polymer membranes as a more energy efficient alternative to amine adsorption. These membranes are relatively inexpensive and easy to work with, but current commercial membranes have low carbon dioxide permeability. To overcome this, scientists have developed hybrid membranes that are part polymer and part metal-organic framework. These hybrids harness the carbon dioxide selectivity of metal-organic frameworks while maintaining the processability of polymers.

But, until now, scientists have not been able to engineer hybrid membranes with enough metal-organic frameworks to form continuous channels through the membrane. This means that, somewhere in a carbon dioxide molecule’s journey through the membrane, the molecule must contact the polymer. This constrains the molecule’s transport to the polymer.

In this latest research, Berkeley Lab scientists have developed a hybrid membrane in which metal-organic frameworks account for 50 percent of its weight, which is about 20 percent more than other hybrid membranes. Previously, the mechanical stability of a hybrid membrane limited the amount of metal-organic frameworks that could be packed in it.

“But we got our membrane to 50 weight percent without compromising its structural integrity,” says Su.

And 50 weight percent appears to be the magic number. At that threshold, there are so many metal organic frameworks in the membrane that they form a continuous network of highways through the membrane. When that happens, the hybrid membrane switches from having a single channel to transport carbon dioxide, in which the molecules must go through the polymer, to two channels, in which the molecules can either move through the polymer or through the metal-organic framework highways.

“This is the first hybrid polymer-MOF membrane to have these dual transport pathways, and it could be a big step toward more competitive carbon capture processes,” says Su.

In addition to fabricating the hybrid membrane at the Molecular Foundry, the scientists analyzed the material at beamline 12.2.2 of the Advanced Light Source.

The research was supported by the Department of Energy’s Office of Science, Berkeley Lab’s Laboratory-Directed Research and Development Program, and the Department of Defense.

The Advanced Light Source and the Molecular Foundry are DOE Office of Science User Facilities located at Berkeley Lab.

###

Lawrence Berkeley National Laboratory addresses the world’s most urgent scientific challenges by advancing sustainable energy, protecting human health, creating new materials, and revealing the origin and fate of the universe. Founded in 1931, Berkeley Lab’s scientific expertise has been recognized with 13 Nobel prizes. The University of California manages Berkeley Lab for the U.S. Department of Energy’s Office of Science. For more, visit www.lbl.gov.

DOE’s Office of Science is the single largest supporter of basic research in the physical sciences in the United States, and is working to address some of the most pressing challenges of our time. For more information, please visit science.energy.gov

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OAK RIDGE, Tenn., March 16, 2016 — Researchers at theDepartment of Energy’s Oak Ridge National Laboratory have combined advanced in-situ microscopy and theoretical calculations to uncover important clues to the properties of a promising next-generation energy storage material for supercapacitors and batteries.

ORNL’s Fluid Interface Reactions, Structures and Transport (FIRST) research team, using scanning probe microscopy made available through the Center for Nanophase Materials Sciences (CNMS) user program, have observed for the first time at the nanoscale and in a liquid environment how ions move and diffuse between layers of a two-dimensional electrode during electrochemical cycling. This migration is critical to understanding how energy is stored in the material, called MXene, and what drives its exceptional energy storage properties.

“We have developed a technique for liquid environments that allows us to track how ions enter the interlayer spaces. There is very little information on how this actually happens,” said Nina Balke, one of a team of researchers working with Drexel University’s Yury Gogotsi in the FIRST Center, a DOE Office of Science Energy Frontier Research Center.

“The energy storage properties have been characterized on a microscopic scale, but no one knows what happens in the active material on the nanoscale in terms of ion insertion and how this affects stresses and strains in the material,” Balke said.

The so-called MXene material — which acts as a two-dimensional electrode that could be fabricated with the flexibility of a sheet of paper — is based on MAX-phase ceramics, which have been studied for decades. Chemical removal of the “A” layer leaves two-dimensional flakes composed of transition metal layers — the “M” — sandwiching carbon or nitrogen layers (the “X”) in the resulting MXene, which physically resembles graphite.

These MXenes, which have exhibited very high capacitance, or ability to store electrical charge, have only recently been explored as an energy storage medium for advanced batteries.

“The interaction and charge transfer of the ion and the MXene layers is very important for its performance as an energy storage medium. The adsorption processes drive interesting phenomena that govern the mechanisms we observed through scanning probe microscopy,” said FIRST researcher Jeremy Come.

The researchers explored how the ions enter the material, how they move once inside the materials and how they interact with the active material. For example, if cations, which are positively charged, are introduced into the negatively charged MXene material, the material contracts, becoming stiffer.

That observation laid the groundwork for the scanning probe microscopy-based nanoscale characterization. The researchers measured the local changes in stiffness when ions enter the material. There is a direct correlation with the diffusion pattern of ions and the stiffness of the material.

Come noted that the ions are inserted into the electrode in a solution.

“Therefore, we need to work in liquid environment to drive the ions within the MXene material. Then we can measure the mechanical properties in-situ at different stages of charge storage, which gives us direct insight about where the ions are stored,” he said.

Until this study the technique had not been done in a liquid environment.

The processes behind ion insertion and the ionic interactions in the electrode material had been out of reach at the nanoscale until the CNMS scanning probe microscopy group’s studies. The experiments underscore the need for in-situ analysis to understand the nanoscale elastic changes in the 2D material in both dry and wet environments and the effect of ion storage on the energy storage material over time.

The researchers’ next steps are to improve the ionic diffusion paths in the material and explore different materials from the MXene family. Ultimately, the team hopes to understand the process’s fundamental mechanism and mechanical properties, which would allow tuning the energy storage as well as improving the material’s performance and lifetime.

ORNL’s FIRST research team also provided additional calculations and simulations based on density functional theory that support the experimental findings. The work was recently published in the Journal Advanced Energy Materials.

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The research team in addition to Balke and Come and Drexel’s Gogotsi included Michael Naguib, Stephen Jesse, Sergei V. Kalinin, Paul R.C. Kent and Yu Xie, all of ORNL.

The FIRST Center is an Energy Frontier Research Center supported by the DOE Office of Science (Basic Energy Sciences). The Center for Nanophase Materials Sciences and the National Energy Research Scientific Computing Center are DOE Office of Science User Facilities.

UT-Battelle manages ORNL for the DOE’s Office of Science. The Office of Science is the single largest supporter of basic research in the physical sciences in the United States, and is working to address some of the most pressing challenges of our time. For more information, please visit http://science.energy.gov/.

Image:https://www.ornl.gov/sites/default/files/news/images/JCome_MXene.jpg

Image cutline: When a negative bias is applied to a two-dimensional MXene electrode, Li+ ions from the electrolyte migrate in the material via specific channels to the reaction sites, where the electron transfer occurs. Scanning probe microscopy at Oak Ridge National Laboratory has provided the first nanoscale, liquid environment analysis of this energy storage material.

NOTE TO EDITORS: You may read other press releases from Oak Ridge National Laboratory or learn more about the lab athttp://www.ornl.gov/news. Additional information about ORNL is available at the sites below:
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Published on Mar 12, 2016
Jason looks at how Quantum Dot technology has progressed, initially as a research topic and then as a commercial product. He defines what commercial success looks like and outlines future market opportunities for the further success of Quantum Dots. Topics include: Quantum Dot business models, architectures and long term roadmap, regulatory environment and future market opportunities.

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