Researchers at Rice University are on to a relatively simple, low-cost way to pry hydrogen loose from water, using the sun as an energy source. The new system involves channeling high-energy “hot” electrons into a useful purpose before they get a chance to cool down. If the research progresses, that’s great news for the hydrogen […]
18 May 2017
Battery stores energy in nontoxic, noncorrosive aqueous solutions
Researchers from the Harvard John A. Paulson School of Engineering and Applied Sciences (SEAS) have developed a new flow battery that stores energy in organic molecules dissolved in neutral pH water.
This new chemistry allows for a non-toxic, non-corrosive battery with an exceptionally long lifetime and offers the potential to significantly decrease the costs of production.
The research, published in ACS Energy Letters, was led by Michael Aziz, the Gene and Tracy Sykes Professor of Materials and Energy Technologies and Roy Gordon, the Thomas Dudley Cabot Professor of Chemistry and Professor of Materials Science.
Flow batteries store energy in liquid solutions in external tanks — the bigger the tanks, the more energy they store.
18 May 2017
Electrodes containing porous graphene and a niobia composite could help improve electrochemical energy storage in batteries. This is the new finding from researchers at the University of California at Los Angeles who say that the nanopores in the carbon material facilitate charge transport in a battery.
By fine tuning the size of these pores, they can not only optimize this charge transport but also increase the amount of active material in the device, which is an important step forward towards practical applications.
Batteries and supercapacitors are two complementary electrochemical energy-storage technologies. They typically contain positive and negative electrodes with the active electrode materials coated on a metal current collector (normally copper or aluminium foil), a separator between the two electrodes, and an electrolyte that facilitates ion transport.
The electrode materials actively participate in charge (energy) storage, whereas the other components are passive but nevertheless compulsory for making the device work.
Batteries offer high energy density but low power density while supercapacitors provide high power density with low energy density.
Although lithium-ion batteries are the most widely employed batteries today for powering consumer electronics, there is a growing demand for more rapid energy storage (high power) and higher energy density. Researchers are thus looking to create materials that combine the high-energy density of battery materials with the short charging times and long cycle life of supercapacitors.
Such materials need to store a large number of charges (such as Li ions) and have an electrode architecture that can quickly deliver charges (electrons and ions) during a given charge/discharge cycle.
15 May 2017
Researchers from UCLA and the University of Connecticut have designed a new biofriendly energy storage system called a biological supercapacitor, which operates using charged particles, or ions, from fluids in the human body. The device is harmless to the body’s biological systems, and it could lead to longer-lasting cardiac pacemakers and other implantable medical devices. The UCLA team was led by Richard Kaner, a distinguished professor of chemistry and biochemistry, and of materials science and engineering, and the Connecticut researchers were led by James Rusling, a professor of chemistry and cell biology.
A paper about their design was published this week in the journal Advanced Energy Materials. Pacemakers — which help regulate abnormal heart rhythms — and other implantable devices have saved countless lives. But they’re powered by traditional batteries that eventually run out of power and must be replaced, meaning another painful surgery and the accompanying risk of infection. In addition, batteries contain toxic materials that could endanger the patient if they leak.
The researchers propose storing energy in those devices without a battery. The supercapacitor they invented charges using electrolytes from biological fluids like blood serum and urine, and it would work with another device called an energy harvester, which converts heat and motion from the human body into electricity — in much the same way that self-winding watches are powered by the wearer’s body movements. That electricity is then captured by the supercapacitor. “Combining energy harvesters with supercapacitors can provide endless power for lifelong implantable devices that may never need to be replaced,” said Maher El-Kady, a UCLA postdoctoral researcher and a co-author of the study.
Modern pacemakers are typically about 6 to 8 millimeters thick, and about the same diameter as a 50-cent coin; about half of that space is usually occupied by the battery. The new supercapacitor is only 1 micrometer thick — much smaller than the thickness of a human hair — meaning that it could improve implantable devices’ energy efficiency. It also can maintain its performance for a long time, bend and twist inside the body without any mechanical damage, and store more charge than the energy lithium film batteries of comparable size that are currently used in pacemakers. “Unlike batteries that use chemical reactions that involve toxic chemicals and electrolytes to store energy, this new class of biosupercapacitors stores energy by utilizing readily available ions, or charged molecules, from the blood serum,” said Islam Mosa, a Connecticut graduate student and first author of the study.
The new biosupercapacitor comprises a carbon nanomaterial called graphene layered with modified human proteins as an electrode, a conductor through which electricity from the energy harvester can enter or leave. The new platform could eventually also be used to develop next-generation implantable devices to speed up bone growth, promote healing or stimulate the brain, Kaner said.
Although supercapacitors have not yet been widely used in medical devices, the study shows that they may be viable for that purpose. “In order to be effective, battery-free pacemakers must have supercapacitors that can capture, store and transport energy, and commercial supercapacitors are too slow to make it work,” El-Kady said. “Our research focused on custom-designing our supercapacitor to capture energy effectively, and finding a way to make it compatible with the human body.” Among the paper’s other authors are the University of Connecticut’s Challa Kumar, Ashis Basu and Karteek Kadimisetty. The research was supported by the National Institute of Health’s National Institute of Biomedical Imaging and Bioengineering, the NIH’s National Institute of Environmental Health Sciences, and a National Science Foundation EAGER grant. Source and top image: UCLA Engineering
12 May 2017
“The solar energy business has been trying to overcome … challenge for years. The cost of installing solar panels has fallen dramatically but storing the energy produced for later use has been problematic.”
“In a single hour, the amount of power from the sun that strikes the Earth is more than the entire world consumes in an year.” To put that in numbers, from the US Department of Energy Each hour 430 quintillion Joules of energy from the sun hits the Earth. That’s 430 with 18 zeroes after it! In comparison, the total amount of energy that all humans use in a year is 410 quintillion Joules. For context, the average American home used 39 billion Joules of electricity in 2013.
Clearly, we have in our sun “a source of unlimited renewable energy”. But how can we best harness this resource? How can we convert and “store” this energy resource on for sun-less days or at night time … when we also have energy needs?
Now therein lies the challenge!
Would you buy a smartphone that only worked when the sun was shining? Probably not. What it if was only half the cost of your current model: surely an upgrade would be tempting? No, thought not.
The solar energy business has been trying to overcome a similar challenge for years. The cost of installing solar panels has fallen dramatically but storing the energy produced for later use has been problematic.
Now scientists in Sweden have found a new way to store solar energy in chemical liquids. Although still in an early phase, with niche applications, the discovery has the potential to make solar power more practical and widespread.
Until now, solar energy storage has relied on batteries, which have improved in recent years. However, they are still bulky and expensive, and they degrade over time.
Trap and release solar power on demand
A research team from Chalmers University of Technology in Gothenburg made a prototype hybrid device with two parts. It’s made from silica and quartz with tiny fluid channels cut into both sections.
The top part is filled with a liquid that stores solar energy in the chemical bonds of a molecule. This method of storing solar energy remains stable for several months. The energy can be released as heat whenever it is required.
The lower section of the device uses sunlight to heat water which can be used immediately. This combination of storage and water heating means that over 80% of incoming sunlight is converted into usable energy.
Suddenly, solar power looks a lot more practical. Compared to traditional battery storage, the new system is more compact and should prove relatively inexpensive, according to the researchers. The technology is in the early stages of development and may not be ready for domestic and business use for some time.
From the lab to off-grid power stations or satellites?
The researchers wrote in the journal Energy & Environmental Science: “This energy can be transported, and delivered in very precise amounts with high reliability(…) As is the case with any new technology, initial applications will be in niches where [molecular storage] offers unique technical properties and where cost-per-joule is of lesser importance.”
The team now plans to test the real-world performance of the technology and estimate how much it will cost. Initially, the device could be used in off-grid power stations, extreme environments, and satellite thermal control systems.
Editor’s Note: As Solomon wrote in Ecclesiastes 1:9: “What has been will be again, what has been done will be done again; there is nothing new under the sun.”
Storing Solar Energy chemically and converting ‘waste heat’ has and is the subject of many research and implementation Projects around the globe. Will this method prove to be “the one?” This writer (IMHO) sees limited application, but not a broadly accepted and integrated solution.
Solar Energy to Hydrogen Fuel
So where does that leave us? We have been following the efforts of a number of Researchers/ Universities who are exploring and developing “Sunlight to Hydrogen Fuel” technologies to harness the enormous and almost inexhaustible energy source power-house … our sun! What do you think? Please leave us your Comments and we will share the results with our readers!
We have written and posted extensively about ‘Solar to Hydrogen Renewable Energy’ – here are some of our previous Posts:
HyperSolar has achieved a major milestone with its hybrid technology HyperSolar, a company that specializes in combining hydrogen fuel cells with solar energy, has reached a significant milestone in terms of hydrogen production. The company harnesses the power of the sun in order to generate the electrical power needed to produce hydrogen fuel. This is […]
Rice University researchers have demonstrated an efficient new way to capture the energy from sunlight and convert it into clean, renewable energy by splitting water molecules. The technology, which is described online in the American Chemical Society journal Nano Letters, relies on a configuration of light-activated gold nanoparticles that harvest sunlight and transfer solar energy […]
NREL researchers Myles Steiner (left), John Turner, Todd Deutsch and James Young stand in front of an atmospheric pressure MDCVD reactor used to grow crystalline semiconductor structures. They are co-authors of the paper “Direct Solar-to-Hydrogen Conversion via Inverted Metamorphic Multijunction Semiconductor Architectures” published in Nature Energy. Photo by Dennis Schroeder. Scientists at the U.S. […]
Photo shows a lead sulfide quantum dot solar cell. A lead sulfide quantum dot solar cell developed by researchers at NREL. Photo by Dennis Schroeder.
Scientists at the U.S. Department of Energy’s National Renewable Energy Laboratory (NREL) have developed a proof-of-principle photo-electro-chemical cell capable of capturing excess photon energy normally lost to generating heat. Using quantum […]