IMAGE: SAMPLES OF NANOHYBRIDS OBTAINED IN NUST MISIS “INORGANIC NANOMATERIALS ” LABORATORY view more CREDIT: ©NUST MISIS
NATIONAL UNIVERSITY OF SCIENCE AND TECHNOLOGY MISIS
Scientists from the National University of Science and Technology MISIS (NUST MISIS), the State Research Center for Applied Microbiology and Biotechnology and the Queensland University (Brisbane, Australia) have created BN/Ag hybrid nanomaterials and have proved their effectiveness as catalysts and antibacterial agents as well as for treating oncological diseases. The results are published in the Beilstein Journal of Nanotechnology.
The interest in the nanomaterials is related to the fact that when a particle is decreased to nanometers (1 nanometer = 10-9 meter) its electronic structure changes, and the material acquires new physical and chemical properties. For example, a magneto can lose its magnetism completely when decreased to ten nanometers.
Today, scientists are beginning to study combinations of various materials at the nanolevel instead of as separate nanoparticles (fullerenes and nanotubes). They have come up with a concept of hybrid nanomaterials, which combine the properties of individual components.
Hybridization makes it possible to combine properties that were incompatible before, for example, to create a material that can be a solid and a plastic at the same time. In addition, the scientists noted that combinations of nanomaterials often showed better or even new properties. Today the nanohybrid area is only beginning to develop.
MISIS scientists are studying the properties of BN hybrid nanomaterials. BN (boron nitride) was chosen as the base for new hybrid nanoparticles because it is chemically inert and biocompatible and has low relative density.
BN hybrid nanomaterials are used as prospective key components of the next generation advanced biomaterials, catalysts and sensors. These hybrids have advantageous combination of properties, such as biocompatibility, high tensile strength and thermal conductivity as well as superb chemical stability and electrical insulation. This explains their rich functionality for developing new biomedicines, reinforcement of ultralight metals and polymers and production of transparent superhydrophobic films and quantum devices.
“We have studied BN/Ag nanohybrid properties and have discovered a high potential for new applications. We were especially interested in an application for treating oncological diseases as well as their activity as catalysts and antibacterial agents,” said Andrei Matveyev, a research author, Senior Research Fellow at the MISIS Inorganic Materials Laboratory.
According to Matveyev, these nanohybrids can be used in cancer therapy as a base for drug delivery medicines. The nanohybrids with the drug become containers to be delivered inside cancer cells. Nanohybrids are chemically modified by attaching folic acid (vitamin ?9) to its surface through an Ag nanoparticle.
The modified nanohybrids with folic acid are mostly accumulated in cancer cells, because they have an increased number of folic acid receptors, so the concentration grows thousand times higher than in healthy cells. In addition, the acidity in a cancer cell is also higher than in the intercellular space, which leads to the drug’s release from its nanocontainer.
“This is why the drug is mostly released inside cancer cells, which decreases the general concentration of the drug in the organism, thus preventing toxicity,” Matveyev notes.
The authors believe that nanohybrids modified for drug delivery can be applied to uses in isotope and neuron capture cancer therapy.
The synthesized particles have also demonstrated high antibacterial activity against test bacteria: Escherichia coli live in dirty water, so water disinfection by nanohybrids may prove useful in emergencies or during war time.
Nanohybrids based on BN/Ag nanoparticles can also be used as an ultraviolet photoactive material.
21 Feb 2018
University of Texas at Austin. This is the world’s thinnest wearable Health Monitor, designed and developed by the researchers at the University of Texas at Austin, in the form of a “Graphene-Ink Tattoo”.
Most health monitors in use today are bulky and tend to restrict patients movements. This graphene tattoo will eliminate these restrictions. It picks up electric signal given off by the body and transmits it to a smartphone app.
Rice University scientists who introduced laser-induced graphene (LIG) have enhanced their technique to produce what may become a new class of edible electronics.
The Rice lab of chemist James Tour, which once turned Girl Scout cookies into graphene, is investigating ways to write graphene patterns onto food and other materials to quickly embed conductive identification tags and sensors into the products themselves.
“This is not ink,” Tour said. “This is taking the material itself and converting it into graphene.” Read More: Rice University Expands LIG (laser induced graphene) Research
Automated, unmanned drones are poised to revolutionize the package delivery industry, with a number of companies already testing drone-based delivery methods.
A new study in Nature Communications looks at the climate impact of a shift from truck-based to drone-based package delivery. It finds that while small drones carrying packages weighing less than 0.5 kg would reduce greenhouse gas emissions compared to diesel or electric trucks anywhere in the U.S., the same is not true for larger drones carrying heavier packages.
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Tenka Energy, Inc. Building Ultra-Thin Energy Dense SuperCaps and NexGen Nano-Enabled Pouch & Cylindrical Batteries – Energy Storage Made Small and POWERFUL! YouTube Video
Stanford University: Lithium/graphene “foil” makes for a great battery electrode – 2X current Energy Density
Graphene handles the issues that come with an electrode’s lithium moving elsewhere.
Lithium ion batteries, as the name implies, work by shuffling lithium atoms between a battery’s two electrodes. So, increasing a battery’s capacity is largely about finding ways to put more lithium into those electrodes. These efforts, however, have run into significant problems.
If lithium is a large fraction of your electrode material, then moving it out can cause the electrode to shrink. Moving it back in can lead to lithium deposits in the wrong places, shorting out the battery. Read More …
Despite being a promising electrode material, bulk cobalt oxide (Co3O4) exhibits poor lithium ion storage properties. Nanostructuring, e.g. making Co3O4 into ultrathin nanosheets, shows improved performance, however, Co3O4-based nanomaterials still lack long-term stability and high rate capability due to sluggish ion transport and structure degradation. Read More …
MIT: Device makes power conversion more efficient New design could dramatically cut energy waste in electric vehicles, data centers, and the power grid
Power electronics, which do things like modify voltages or convert between direct and alternating current, are everywhere. They’re in the power bricks we use to charge our portable devices; they’re in the battery packs of electric cars; and they’re in the power grid itself, where they mediate between high-voltage transmission lines and the lower voltages of household electrical sockets. Read More …
Elon Musk and Tesla have made some bold claims for the new Tesla Semi and Roadster. Those who understand batteries have been scratching their heads trying to figure out how the company can deliver the specs it’s promising – and concluding that the only possible way is some as-yet-unannounced advancement in battery technology. Read More …
Watch Our Video on New Energy Storage Technology: Supercapacitors and Batteries
20 Jul 2017
Genesis Nanotechnology, Inc.
“Great Things from Small Things” ~ GNT™
Read this edition of Genesis Nanotechnology Online featuring:
14 Jul 2017
Original Report from IDTechEX
Volvo Cars has been in the news recently in relation to their announcement this Wednesday on their decision to leave the internal combustion engine only based automotive industry. The Chinese-European company announced that from 2019 all their vehicles will be either pure electric or hybrid electric. In this way it has been argued the company is making a bold move towards electrification of vehicles. Volvo to capture potential market in China The company will launch a pure electric car in 2019 and that is a great move indeed, considering that the company has been owned by Chinese vehicle manufacturer Geely since 2010.
The Chinese electric vehicle market has been booming in the last years reaching a sales level of 350,000 plug-in EVs (pure electric and plug-in hybrid electric cars) in 2016. The Chinese plug-in EV market grew 300% from 2014 to 2015 but cooled down to 69% growth in 2016 vs 2015, still pushing a triple digit growth in pure electric cars. The Chinese government has announced that in 2017 sales will reach 800,000 NEV (new energy vehicles including passenger and bus, both pure electric and hybrid electric). IDTechEx believes that China will not make it to that level, but will definitely push the figures close to that mark.
We think that the global plug-in electric vehicle market will surpass 1 million sales per year for the first time at the end of 2017. Until recently this market has been mostly dominated by Chinese manufacturers, being BYD the best seller of electric cars in the country with 100,000 plug-in EVs sold in 2016. Tesla polemically could not penetrate the market but in 2016 sold around 11,000 units.
Whilst the owner of Volvo Cars, Geely, is active in China selling around 17,000 pure electric cars per year, it might be that Volvo has now realized that they can leverage on their brand in the Chinese premium market to catch the huge growth opportunity in China and need to participate as soon as possible. More information on market forecasts can be found in IDTechEx Research’s report Electric Vehicles 2017-2037: Forecasts, Analysis and Opportunities.
Is Volvo Cars’ move a revolutionary one? Not really, as technically speaking the company is not entirely making a bold movement to only 100% “strong” hybrid electric and pure electric vehicles. This is because the company will launch in 2019 a “mild” hybrid electric vehicles,this is also known in the industry as 48V hybrid electric platform. This is a stepping stone between traditional internal combustion engine companies and “strong” hybrid electric vehicles such as the Toyota Prius.
The 48V platform is being adopted by many automotive manufacturers, not only Volvo. OEMs like Continental developed this platform to provide a “bridge technology” towards full EVs for automotive manufacturers, providing 6 to 20 kW electric assistance. By comparison, a full hybrid system typically offers 20-40-kW and a plug-in hybrid, 50-90 kW. Volvo had already launched the first diesel plug-in hybrid in 2012 and the company will launch a new plug-in hybrid platform in 2018 in addition to the launch of the 2019 pure electric vehicle platform. Going only pure electric and plug-in hybrid electric would be really revolutionary. See IDTechEx Research’s report Mild Hybrid 48V Vehicles 2017-2027 for more information on 48V platforms.
Additional Information: The Tesla Model ‘S’
The Tesla Model S is a full-sized all-electric five-door, luxury liftback, produced by Tesla, Inc., and introduced on 22 June 2012. It scored a perfect 5.0 NHTSA automobile safety rating. The EPA official rangefor the 2017 Model S 100D, which is equipped with a 100 kWh(360 MJ) battery pack, is 335 miles (539 km), higher than any other electric car. The EPA rated the 2017 90D Model S’s energy consumption at 200.9 watt-hours per kilometer (32.33 kWh/100 mi or 20.09 kWh/100 km) for a combined fuel economy of 104 miles per gallon gasoline equivalent (2.26 L/100 km or 125 mpg‑imp). In 2016, Tesla updated the design of the Model S to closely match that of the Model X. As of July 2017, the following versions are available: 75, 75D, 90D, 100D and P100D.
For more specific details on the updated Tesla Battery Pack go here:
A radical move would be to drop diesel engines On-road diesel vehiclesproduce approximately 20% of global anthropogenic emissions of nitrogen oxides (NOx), which are key PM and ozone precursors. Diesel emission pollutions has been confirmed as a major source of premature mortality. A recent study published in Nature by the Environmental Health Analytics LLC and the International Council on Clean Transportation both based in Washington, USA found that whilst regulated NOx emission limits in leading markets have been progressively tightened, current diesel vehicles emit far more NOx under real-world operating conditions than during laboratory certification testing. The authors show that across 11 markets, representing approximately 80% of global diesel vehicle sales, nearly one-third of on-road heavy-duty diesel vehicle emissions and over half of on-road light-duty diesel vehicle emissions are in excess of certification limits. These emissions were associated with about 38,000 premature deaths globally in 2015.
The authors conclude that more stringent standards are required in order to avoid 174,000 premature deaths globally in 2040. Diesel cars account for over 50 percent of all new registrations in Europe, making the region by far the world’s biggest diesel market. Volvo Cars, sells 90 percent of its XC 90 off roaders in Europe with diesel engines. “From today’s perspective, we will not develop any more new generation diesel engines,” said Volvo’s CEO Hakan Samuelsson told German’s Frankfurter Allgemeine Zeitung in an interview . Samuelsson declared that Volvo Cars aims to sell 1 million “electrified” cars by 2025, nevertheless he refused to be drawn on when Volvo Cars will sell its last diesel powered vehicle.
Goldman Sachs believes a regulatory crackdown could add 300 euros ($325) per engine to diesel costs that are already some 1,300 euros above their petrol-powered equivalents, as carmakers race to bring real NOx emissions closer to their much lower test-bench scores. Scandinavia’s vision of a CO2-free economy Volvo’s decision should also be placed in a wider context regarding the transition to an environmentally sustainable economy.
Scandinavia’s paper industry has made great strides towards marketing itself as green and eco-aware in the last decades, so much so that countries like Norway have tripled the amount of standing wood in forests compared to 100 years ago. Energy supply is also an overarching theme, with each one of the four Scandinavian countries producing more than 39% of their electricity with renewables (Finland 39%, Sweden and Denmark 56%, Norway 98%). Finally, strong public incentives have made it possible for electric vehicles to become a mainstream market in Norway, where in 2016, one in four cars sold was a plug-in electric, either pure or hybrid. It is then of no surprise that the first battery Gigafactory announcement in Europe came from a Swedish company called Northvolt (previously SGF Energy).
The Li-ion factory will open in 4 steps, with each one adding 8 GWh of production capacity. This gives a projected final output of 32 GWh, but if higher energy cathodes are developed, 40-50 GWh capacity can be envisioned. A site has not yet been identified, but the choice has been narrowed down to 6-7 locations, all of them in the Scandinavian region. The main reasons to establish a Gigafactory there boil down to the low electricity prices (hydroelectric energy), presence of relevant mining sites, and the presence of local know-how from the pulp & paper industry. After a long search for a European champion in the EV market, it finally seems that Sweden has accepted to take the lead, and compete with giants like BYD and rising stars like Tesla. This could be the wake-up call for many other European car makers, which have been rather bearish towards EV acceptance despite many bold announcements. To learn more about IDTechEx’s view on electric vehicles, and our projections up to 2037, please check our master report on the subject http://www.IDTechEx.com/ev .
Top image source: Volvo Cars Learn more at the next leading event on the topic: Business and Technology Insight Forum. Korea 2017 on 19 – 21 Sep 2017 in Seoul, Korea hosted by IDTechEx.
More Information on ‘NextGen Magnum SuperCap-Battery Pack’ that could propel a Tesla Model ‘S’ 90% farther (almost double) and cost 1/2 (one-half) as much: Video
11 Jul 2017
Through nanotechnology, physicists Dr Raymond McQuaid, Dr Amit Kumar and Professor Marty Gregg from Queen’s University’s School of Mathematics and Physics, have created unique 2-D sheets, called domain walls, which exist within crystalline materials.
The sheets are almost as thin as the wonder-material graphene, at just a few atomic layers. However, they can do something that graphene can’t – they can appear, disappear or move around within the crystal, without permanently altering the crystal itself.
This means that in future, even smaller electronic devices could be created, as electronic circuits could constantly reconfigure themselves to perform a number of tasks, rather than just having a sole function.
Professor Marty Gregg explains: “Almost all aspects of modern life such as communication, healthcare, finance and entertainment rely on microelectronic devices.
The demand for more powerful, smaller technology keeps growing, meaning that the tiniest devices are now composed of just a few atoms – a tiny fraction of the width of human hair.”
“As things currently stand, it will become impossible to make these devices any smaller – we will simply run out of space. This is a huge problem for the computing industry and new, radical, disruptive technologies are needed. One solution is to make electronic circuits more ‘flexible’ so that they can exist at one moment for one purpose, but can be completely reconfigured the next moment for another purpose.”
The team’s findings, which have been published in Nature Communications, pave the way for a completely new way of data processing.
Professor Gregg says: “Our research suggests the possibility to “etch-a-sketch” nanoscale electrical connections, where patterns of electrically conducting wires can be drawn and then wiped away again as often as required.
“In this way, complete electronic circuits could be created and then dynamically reconfigured when needed to carry out a different role, overturning the paradigm that electronic circuits need be fixed components of hardware, typically designed with a dedicated purpose in mind.”
There are two key hurdles to overcome when creating these 2-D sheets, long straight walls need to be created. These need to effectively conduct electricity and mimic the behavior of real metallic wires. It is also essential to be able to choose exactly where and when the domain walls appear and to reposition or delete them.
Through the research, the Queen’s researchers have discovered some solutions to the hurdles. Their research proves that long conducting sheets can be created by squeezing the crystal at precisely the location they are required, using a targeted acupuncture-like approach with a sharp needle. The sheets can then be moved around within the crystal using applied electric fields to position them.
Dr Raymond McQuaid, a recently appointed lecturer in the School of Mathematics and Physics at Queen’s University, added: “Our team has demonstrated for the first time that copper-chlorine boracite crystals can have straight conducting walls that are hundreds of microns in length and yet only nanometres thick.
The key is that, when a needle is pressed into the crystal surface, a jigsaw puzzle-like pattern of structural variants, called “domains”, develops around the contact point. The different pieces of the pattern fit together in a unique way with the result that the conducting walls are found along certain boundaries where they meet.
“We have also shown that these walls can then be moved using applied electric fields, therefore suggesting compatibility with more conventional voltage operated devices. Taken together, these two results are a promising sign for the potential use of conducting walls in reconfigurable nano-electronics.”
More information: Raymond G.P. McQuaid et al. Injection and controlled motion of conducting domain walls in improper ferroelectric Cu-Cl boracite, Nature Communications (2017). DOI: 10.1038/ncomms15105
Provided by: Queen’s University Belfast
11 Jul 2017
New research shows graphene can filter common salts from water to make it safe to drink Findings could lead to affordable desalination technology
Graphene-oxide membranes have attracted considerable attention as promising candidates for new filtration technologies. Now the much sought-after development of making membranes capable of sieving common salts has been achieved.
New research demonstrates the real-world potential of providing clean drinking water for millions of people who struggle to access adequate clean water sources.
The new findings from a group of scientists at The University of Manchester were published today in the journal Nature Nanotechnology.
Previously graphene-oxide membranes have shown exciting potential for gas separation and water filtration.
Graphene-oxide membranes developed at the National Graphene Institute have already demonstrated the potential of filtering out small nanoparticles, organic molecules, and even large salts. Until now, however, they couldn’t be used for sieving common salts used in desalination technologies, which require even smaller sieves.
Previous research at The University of Manchester found that if immersed in water, graphene-oxide membranes become slightly swollen and smaller salts flow through the membrane along with water, but larger ions or molecules are blocked.
The Manchester-based group have now further developed these graphene membranes and found a strategy to avoid the swelling of the membrane when exposed to water.
The pore size in the membrane can be precisely controlled which can sieve common salts out of salty water and make it safe to drink.
Realisation of scalable membranes with uniform pore size down to atomic scale is a significant step forward and will open new possibilities for improving the efficiency of desalination technology.
Professor Rahul Raveendran Nair
As the effects of climate change continue to reduce modern city’s water supplies, wealthy modern countries are also investing in desalination technologies. Following the severe floods in California major wealthy cities are also looking increasingly to alternative water solutions.
When the common salts are dissolved in water, they always form a ‘shell’ of water molecules around the salts molecules. This allows the tiny capillaries of the graphene-oxide membranes to block the salt from flowing along with the water. Water molecules are able to pass through the membrane barrier and flow anomalously fast which is ideal for application of these membranes for desalination.
Professor Rahul Nair, at The University of Manchester said: “Realisation of scalable membranes with uniform pore size down to atomic scale is a significant step forward and will open new possibilities for improving the efficiency of desalination technology.
“This is the first clear-cut experiment in this regime. We also demonstrate that there are realistic possibilities to scale up the described approach and mass produce graphene-based membranes with required sieve sizes.”
Mr. Jijo Abraham and Dr. Vasu Siddeswara Kalangi were the joint-lead authors on the research paper: “The developed membranes are not only useful for desalination, but the atomic scale tunability of the pore size also opens new opportunity to fabricate membranes with on-demand filtration capable of filtering out ions according to their sizes.” said Mr. Abraham.
By 2025 the UN expects that 14% of the world’s population will encounter water scarcity. This technology has the potential to revolutionise water filtration across the world, in particular in countries which cannot afford large scale desalination plants.
It is hoped that graphene-oxide membrane systems can be built on smaller scales making this technology accessible to countries which do not have the financial infrastructure to fund large plants without compromising the yield of fresh water produced.
A UK-based team of researchers has created a graphene-based sieve capable of removing salt from seawater.
The sought-after development could aid the millions of people without ready access to clean drinking water. The promising graphene oxide sieve could be highly efficient at filtering salts, and will now be tested against existing desalination membranes.
It has previously been difficult to manufacture graphene-based barriers on an industrial scale. Reporting their results in the journal Nature Nanotechnology, scientists from the University of Manchester, led by Dr Rahul Nair, shows how they solved some of the challenges by using a chemical derivative called graphene oxide.
Advanced materials is one of The University of Manchester’s research beacons – examples of pioneering discoveries, interdisciplinary collaboration and cross-sector partnerships that are tackling some of the biggest questions facing the planet. #ResearchBeacons
17 Jun 2017
Tesla is revolutionizing batteries for electric bicycles and it has to do with the recent changes at the leading battery cell makers BMZ, Panasonic, Sony, Samsung and LG. Together these five make out some 80% of the world production of battery cells.
These five cell makers used to supply huge numbers of cylindrical shaped cells to the IT industry until the industry changed completely from using cylindrical shaped cells to flat shaped batteries which are now used in laptops, tablets and smartphones. Tesla placing huge orders for cylindrical shaped cells pushed battery cell makers to new highs.
Europe’s largest battery maker BMZ boss introduced the 21700 cell that will revolutionize electric bicycles. In particular as the 21700 cell not only offers a much prolonged lifetime but also batteries with a much bigger capacity for more power and pedal-supported mileage.
The extraordinary features that the 21700 battery cell brings to e-bikes will be the new standard in e-bike batteries. And that this new standard will already be available in 2018.
Instead of the current 18650 (18mm diameter and 65mm high) cell size the 21700 cell is 21mm diameter and 70mm high. The bigger size is bringing a bigger output; up to 4.8Ah. With that capacity the battery lifetime is extended from the current some 500 charging cycles up to 1,500 to 2,000 cycles.
BMZ, together with another global battery player, managed to develop batteries that offer a much longer lifespan thanks to the fact that the new batteries create less heat and has up to 60% more capacity.
Researchers have developed a solar paint that can absorb water vapour and split it to generate hydrogen – the cleanest source of energy.
The paint contains a newly developed compound that acts like silica gel, which is used in sachets to absorb moisture and keep food, medicines and electronics fresh and dry.
But unlike silica gel, the new material, synthetic molybdenum-sulphide, also acts as a semi-conductor and catalyses the splitting of water atoms into hydrogen and oxygen.
Lead researcher Dr Torben Daeneke, from RMIT University in Melbourne, Australia, said: “We found that mixing the compound with titanium oxide particles leads to a sunlight-absorbing paint that produces hydrogen fuel from solar energy and moist air.
“Titanium oxide is the white pigment that is already commonly used in wall paint, meaning that the simple addition of the new material can convert a brick wall into energy harvesting and fuel production real estate.
“Our new development has a big range of advantages,” he said. “There’s no need for clean or filtered water to feed the system. Any place that has water vapour in the air, even remote areas far from water, can produce fuel.”
His colleague, Distinguished Professor Kourosh Kalantar-zadeh, said hydrogen was the cleanest source of energy and could be used in fuel cells as well as conventional combustion engines as an alternative to fossil fuels.
“This system can also be used in very dry but hot climates near oceans. The sea water is evaporated by the hot sunlight and the vapour can then be absorbed to produce fuel.
“This is an extraordinary concept – making fuel from the sun and water vapour in the air.”
More information: Torben Daeneke et al, Surface Water Dependent Properties of Sulfur-Rich Molybdenum Sulfides:
Electrolyteless Gas Phase Water Splitting, ACS Nano (2017). DOI: 10.1021/acsnano.7b01632
Provided by: RMIT University