03 Mar 2016
“Our climate change solution is two fold: To transform the greenhouse gas carbon dioxide into valuable products and to provide greenhouse gas emission-free alternatives to today’s industrial and transportation fossil fuel processes,” Stuart Licht, professor of chemistry at George Washington University
An interdisciplinary team of scientists has worked out a way to make electric vehicles that are not only carbon neutral, but carbon negative, capable of actually reducing the amount of atmospheric carbon dioxide as they operate. They have done so by demonstrating how the graphite electrodes used in the lithium-ion batteries that power electric automobiles can be replaced with carbon material recovered from the atmosphere.
The recipe for converting carbon dioxide gas into batteries is described in a paper published in the March 2 issue of the journal ACS Central Science (“Carbon Nanotubes Produced from Ambient Carbon Dioxide for Environmentally Sustainable Lithium-Ion and Sodium-Ion Battery Anodes”).
The Solar Thermal Electrochemical Process (STEP) converts atmospheric carbon dioxide into carbon nanotubes that can be used in advanced batteries. (Image: Julie Turner, Vanderbilt University)
“Our climate change solution is two fold: To transform the greenhouse gas carbon dioxide into valuable products and to provide greenhouse gas emission-free alternatives to today’s industrial and transportation fossil fuel processes,” Stuart Licht, professor of chemistry at George Washington University said.
“In addition to better batteries other applications for the carbon nanotubes include carbon composites for strong, lightweight construction materials, sports equipment and car, truck and airplane bodies.” The unusual pairing of carbon dioxide conversion and advanced battery technology is the result of a collaboration between Dr. Licht, and the laboratory of assistant professor of mechanical engineering Cary Pint at Vanderbilt University. Licht adapted the lab’s solar thermal electrochemical process (STEP) so that it produces carbon nanotubes from carbon dioxide and with Pint by incorporating them into both lithium-ion batteries like those used in electric vehicles and electronic devices and low-cost sodium-ion batteries under development for large-scale applications, such as the electric grid. In lithium-ion batteries, the nanotubes replace the carbon anode used in commercial batteries.
The team demonstrated that the carbon nanotubes gave a small boost to the performance, which was amplified when the battery was charged quickly. In sodium-ion batteries, the researchers found that small defects in the carbon, which can be tuned by STEP, can unlock stable storage performance over 3.5 times above that of sodium-ion batteries with graphite electrodes. Most importantly, both carbon-nanotube batteries were exposed to about 2.5 months of continuous charging and discharging and showed no sign of fatigue.
Published on Feb 25, 2016: Video interview with Cary Pint explaining this research.
Scientists from Vanderbilt and George Washington universities have worked out a way to make electric vehicles not just carbon neutral but carbon negative by demonstrating how the graphite electrodes used in the lithium-ion batteries can be replaced with carbon recovered from the atmosphere.
|“This trailblazing research has achieved yet another amazing milestone with the incorporation of the carbon nanotubes produced by Stuart Licht’s STEP reduction of carbon dioxide process into batteries for electric vehicles and large scale storage,” said Michael King, chair of GW’s Department of Chemistry. “We are thrilled by this translation of basic research into potentially useful consumer products while mitigating atmospheric carbon dioxide buildup. This is a win-win for everyone!”|
|The researchers estimate that with a battery cost of $325 per kWh (the average cost of lithium-ion batteries reported by the Department of Energy in 2013), a kilogram of carbon dioxide has a value of about $18 as a battery material – six times more than when it is converted to methanol – a number that only increases when moving from large batteries used in electric vehicles to the smaller batteries used in electronics.
And unlike methanol, combining batteries with solar cells provides renewable power with zero greenhouse emissions, which is needed to put an end to the current carbon cycle that threatens future global sustainability.
|Licht also proposes a modified flue system for combustion plants that incorporates this process could be self-sustaining, as exemplified by a new natural gas power plant with zero carbon dioxide emissions. That’s because the side product of the process is pure oxygen, which plants could then use for further combustion. The calculated total cost per metric tonne of CNTs would be much less expensive than current synthetic methods.|
|“This approach not only produces better batteries but it also establishes a value for carbon dioxide recovered from the atmosphere that is associated with the end-user battery cost unlike most efforts to reuse CO2 that are aimed at low-valued fuels, like methanol, that cannot justify the cost required to produce them,” said Pint.|
|Source: Vanderbilt University|
Genesis Nanotechnology, Inc. ~ “Great Things from Small Things”
In the latest edition of their annual letter published today, Bill and Melinda Gates argue that the world needs “an energy miracle,” and are willing to bet that such a breakthrough will arrive within 15 years.
Bill Gates cites scientists’ estimates that to avoid the worst effects of climate change the biggest carbon-emitting countries must reduce greenhouse gas emissions by 80% by 2050, and the world must more or less stop such emissions entirely by 2100. And that’s not going to happen if we continue on our current trajectory.
You can see Gates explain the equation in the Quartz video above.
Gates says he was stunned to discover how little research and development money is going toward breakthroughs in cheaper, scaleable clean-energy sources.Gates announced last year that he was committing $1 billion of his own money over five years to invest in clean-energy technology, and has been pushing governments to increase their funding.
To explain the need for a breakthrough in energy technology, he uses an equation (similar to the Kaya identity equation) that represents the factors determining how much carbon dioxide the world emits every year.
“Within the next 15 years, I expect the world will discover a clean-energy breakthrough that will save our planet and power our world.” Gates believes that cleaner options such as electric cars and LED lighting won’t bring down energy consumption enough to hit those climate-change goals. In fact, he doesn’t see any current clean-energy technology that will enable the world to eliminate carbon dioxide emissions by 2100, partly because it’s not consistent or inexpensive enough.
Gates has personally invested in next-generation nuclear power technology, which he describes as “a very promising path.” He is also backing efforts to improve battery technology, so that energy from intermittent clean sources such as solar and wind can be stored affordably at large scale for use over time. “I think we need to pursue many different paths,” says Gates in an interview with Quartz.
And he’s betting on relatively fast progress. “Within the next 15 years,” Gates predicts in his letter, “I expect the world will discover a clean-energy breakthrough that will save our planet and power our world.”
** Re-Posted from the World Economic Forum
Genesis Nanotechnology, Inc. ~ “Great Things from Small Things”