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riceresearch Solar Water Split 090415Rice University researchers have demonstrated an efficient new way to capture the energy from sunlight and convert it into clean, renewable energy by splitting water molecules.

The technology, which is described online in the American Chemical Society journal Nano Letters, relies on a configuration of light-activated gold nanoparticles that harvest sunlight and transfer solar energy to highly excited electrons, which scientists sometimes refer to as “hot electrons.”

“Hot electrons have the potential to drive very useful chemical reactions, but they decay very rapidly, and people have struggled to harness their energy,” said lead researcher Isabell Thomann, assistant professor of electrical and computer engineering and of chemistry and materials science and nanoengineering at Rice. “For example, most of the energy losses in today’s best photovoltaic solar panels are the result of hot electrons that cool within a few trillionths of a second and release their energy as wasted heat.”

Capturing these high-energy electrons before they cool could allow solar-energy providers to significantly increase their solar-to-electric power-conversion efficiencies and meet a national goal of reducing the cost of solar electricity.

In the light-activated nanoparticles studied by Thomann and colleagues at Rice’s Laboratory for Nanophotonics (LANP), light is captured and converted into plasmons, waves of electrons that flow like a fluid across the metal surface of the nanoparticles. Plasmons are high-energy states that are short-lived, but researchers at Rice and elsewhere have found ways to capture plasmonic energy and convert it into useful heat or light. Plasmonic nanoparticles also offer one of the most promising means of harnessing the power of hot electrons, and LANP researchers have made progress toward that goal in several recent studies.

riceresearch Solar Water Split 090415

Rice University researchers have demonstrated an efficient new way to capture the energy from sunlight and convert it into clean, renewable energy by splitting water molecules. Credit: I. Thomann/Rice University 

Thomann and her team, graduate students Hossein Robatjazi, Shah Mohammad Bahauddin and Chloe Doiron, created a system that uses the energy from hot electrons to split molecules of water into oxygen and hydrogen. That’s important because oxygen and hydrogen are the feedstocks for fuel cells, electrochemical devices that produce electricity cleanly and efficiently.

To use the hot electrons, Thomann’s team first had to find a way to separate them from their corresponding “electron holes,” the low-energy states that the hot electrons vacated when they received their plasmonic jolt of energy. One reason hot electrons are so short-lived is that they have a strong tendency to release their newfound energy and revert to their low-energy state. The only way to avoid this is to engineer a system where the hot electrons and electron holes are rapidly separated from one another. The standard way for electrical engineers to do this is to drive the hot electrons over an energy barrier that acts like a one-way valve. Thomann said this approach has inherent inefficiencies, but it is attractive to engineers because it uses well-understood technology called Schottky barriers, a tried-and-true component of electrical engineering.

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