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Moly Berkley Jim-Schuck-MoS2_v5_2_Web-300x300  Scientists with the U.S. Department of Energy (DOE)’s Lawrence Berkeley National Laboratory (Berkeley Lab) have used a unique nano-optical probe to study the effects of illumination on two-dimensional semiconductors at the molecular level. Working at the Molecular Foundry, a DOE Office of Science User Facility, the scientific team used the “Campanile” probe they developed to make some surprising discoveries about molybdenum disulfide, a member of a family of semiconductors, called “transition metal dichalcogenides (TMDCs), whose optoelectronic properties hold great promise for future nanoelectronic and photonic devices.

“The Campanile probe’s remarkable resolution enabled us to identify significant nanoscale optoelectronic heterogeneity in the interior regions of monolayer crystals of molybdenum disulfide, and an unexpected, approximately 300 nanometer wide, energetically disordered edge region,” says James Schuck, a staff scientist with Berkeley Lab’s Materials Sciences Division. Schuck led this study as well as the team that created the Campanile probe, which won a prestigious R&D 100 Award in 2013 for combining the advantages of scan/probe microscopy and optical spectroscopy.

“This disordered edge region, which has never been seen before, could be extremely important for any devices in which one wants to make electrical contacts,” Schuck says. “It might also prove critical to photocatalytic and nonlinear optical conversion applications.”

(From left)Jim Schuck, Wei Bao and Nicholas Borys at the Molecular Foundry where they made surprising discoveries about 2D MoS2, a promising TMDC semiconductor for future photonic and nanoelectronic devices. (Photo by Roy Kaltschmidt)

Schuck, who directs the Imaging and Manipulation of Nanostructures Facility at the Molecular Foundry, is the corresponding author of a paper describing this research in Nature Communications. The paper is titled “Visualizing nanoscale excitonic relaxation properties of disordered edges and grain boundaries in monolayer molybdenum disulfide.” The co-lead authors are Wei Bao and Nicholas Borys. (See below for a complete list of authors.)

2D-TMDCs rival graphene as potential successors to silicon for the next generation of high-speed electronics. Only a single molecule in thickness, 2D-TMDC materials boast superior energy efficiencies and a capacity to carry much higher current densities than silicon. However, since their experimental “discovery” in 2010, the performance of 2D-TMDC materials has lagged far behind theoretical expectations primarily because of a lack of understanding of 2D-TMDC properties at the nanoscale, particularly their excitonic properties. Excitons are bound pairs of excited electrons and holes that enable semiconductors to function in devices.

“The poor understanding of 2D-TMDC excitonic and other properties at the nanoscale is rooted in large part to the existing constraints on nanospectroscopic imaging,” Schuck says. “With our Campanile probe, we overcome nearly all previous limitations of near-field microscopy and are able to map critical chemical and optical properties and processes at their native length scales.”

Campanile-bellsThe Campanile probe, which draws its name from the landmark “Campanile” clock tower on the campus of the University of California at Berkeley, features a tapered, four-sided microscopic tip that is mounted on the end of an optical fiber. Two of the Campanile probe’s sides are coated with gold and the two gold layers are separated by just a few nanometers at the tip. The tapered design enables the Campanile probe to channel light of all wavelengths down into an enhanced field at the apex of the tip. The size of the gap between the gold layers determines the resolution, which can be below the diffraction optical limit.

In their new study, Schuck, Bao, Borys and their co-authors used the Campanile probe to spectroscopically map nanoscale excited-state/relaxation processes in monolayer crystals of molybdenum disulfide that were grown by chemical vapor deposition (CVD). Molybdenum disulfide is a 2D semiconductor that features high electrical conductance comparable to that of graphene, but, unlike graphene, has natural energy band-gaps, which means its conductance can be switched off.

“Our study revealed significant nanoscale optoelectronic heterogeneity and allowed us to quantify exciton-quenching phenomena at crystal grain boundaries,” Schuck said. “The discovery of the disordered edge region constitutes a paradigm shift from the idea that only a 1D metallic edge state is responsible for all the edge-related physics and photochemistry being observed in 2D-TMDCs. What’s happening at the edges of 2D-TMDC crystals is clearly more complicated than that. There’s a   mesoscopic disordered region that likely dominates most transport, nonlinear optical, and photocatalytic behavior near the edges of CVD-grown 2D-TMDCs.”

Comparison between image of MoS2 flake captured with Campanile probe and image of same flake captured with scanning confocal microscopy shows the Campanile probe’s enhanced resolution.

In this study, Schuck and his colleagues also discovered that the disordered edge region in molybdenum disulfide crystals harbors a sulfur deficiency that holds implications for future optoelectronic applications of this 2D-TMDC.

“Less sulfur means more free electrons are present in that edge region, which could lead to enhanced non-radiative recombination,” Schuck says. “Enhanced non-radiative recombination means that excitons created near a sulfur vacancy would live for a much shorter period of time.”

Schuck and his colleagues plan to next study the excitonic and electronic properties that may arise, as well as the creation of p-n junctions and quantum wells, when two disparate types of TMDCs are connected.

“We are also combining 2D-TMDC materials with so-called meta surfaces for controlling and manipulating the valley states and circular emitters that exist within these systems, as well as exploring localized quantum states that could act as near-ideal single-photon emitters and quantum-entangled Qubit states,” Schuck says.

In addition to Schuck, Bao, Borys and Weber-Bargioni, other co-authors of the Nature Communications paper are Changhyun Ko, Joonki Suh, Wen Fan, Andrew Thron, Yingjie Zhang, Alexander Buyanin, Jie Zhang, Stefano Cabrini, Paul Ashby, Alexander Weber-Bargioni, Sefaattin Tongay, Shaul Aloni, Frank Ogletree, Junqiao Wu and Miquel Salmeron.
This research was supported by the DOE Office of Science.

Additional Information

For more about the research of James Schuck and his group go here

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Lawrence Berkeley National Laboratory addresses the world’s most urgent scientific challenges by advancing sustainable energy, protecting human health, creating new materials, and revealing the origin and fate of the universe. Founded in 1931, Berkeley Lab’s scientific expertise has been recognized with 13 Nobel prizes. The University of California manages Berkeley Lab for the U.S. Department of Energy’s Office of Science. For more, visit

MIT-photonics-wafer_bv02_0Partnership of government, industry, and academia will pursue integration of optical devices with electronics.

MIT is a key player in a new $600 million public-private partnership announced today by the Obama administration to help strengthen high-tech U.S.-based manufacturing.

Physically headquartered in New York state and led by the State University of New York Polytechnic Institute (SUNY Poly), the American Institute for Manufacturing Integrated Photonics (AIM Photonics) will bring government, industry, and academia together to advance domestic capabilities in integrated photonic technology and better position the U.S. relative to global competition.

Federal funding of $110 million will be combined with some $500 million from AIM Photonics’ consortium of state and local governments, manufacturing firms, universities, community colleges, and nonprofit organizations across the country.

Technologies that can help to integrate photonics, or light-based communications and computation, with existing electronic systems are seen as a crucial growth area as the world moves toward ever-greater reliance on more powerful high-tech systems. What’s more, many analysts say this is an area that could help breathe new life into a U.S. manufacturing base that has been in decline in recent years.

The public-private partnership announced today aims to spur these twin goals, improving integration of photonic systems while revitalizing U.S. manufacturing. The consortium includes universities, community colleges, and businesses in 20 states. Six state governments, including that of Massachusetts, are also supporting the project.

MIT faculty will manage important parts of the program: Michael Watts, an associate professor of electrical engineering and computer science, will lead the technological innovation in silicon photonics. Lionel Kimerling, the Thomas Lord Professor in Materials Science and Engineering, will lead a program in education and workforce development.

“This is great news on a number of fronts,” MIT Provost Martin Schmidt says. “Photonics holds the key to advances in computing, and its pursuit will engage and energize research and economic activity from Rochester, New York, to Cambridge, Massachusetts, and beyond. MIT faculty are excited to contribute to this effort.”

An ongoing partnership

MIT’s existing collaboration with SUNY Poly led to the first complete 300-millimeter silicon photonics platform, Watts says. That effort has led to numerous subsequent advances in silicon photonics technology, with MIT developing photonic designs that SUNY Poly has then built in its state-of-the-art fabrication facility.

Photonic devices are seen as key to continuing the advances in computing speed and efficiency described by Moore’s Law — which may have reached their theoretical limits in existing silicon-based electronics, Kimerling says. The integration of photonics with electronics promises not only to boost the performance of systems in data centers and high-performance computing, but also to reduce their energy consumption — which already accounts for more than 2 percent of all electricity use in the U.S.

Kimerling points out that a single new high-performance computer installation can contain more than 1 million photonic connections between hundreds of thousands of computer processor units (CPUs). “That’s more than the entire telecommunications industry,” he says — so creating new, inexpensive, and energy-efficient connection systems at scale is a major need.

The integration of such systems has been progressing in stages, Kimerling says. Initially, the conversion from optical to electronic signals became pervasive at the network level to support long-distance telecommunication, but it is now moving to circuit boards, and will ultimately go to the level of individual integrated-circuit chips.

“Europe is ahead in industry coordination right now,” following a decade of government investment, Kimerling says. This new U.S. initiative, he says, is “one of the first of this kind in the U.S., and the bet is that the innovation and research here, combined with the manufacturing capability, will allow our companies to really take off.”

Leadership in technological innovation

Within the new alliance, MIT will lead technological innovation in silicon photonics. That task will be managed by Watts.

The evolving integration of photonics and electronics will have a great impact on many different technologies, Watts says. For example, LIDAR systems — similar to radar, but using light beams instead of radio waves — have great potential for collision-avoidance systems in cars, since they can provide greater detail than radar or sonar. Watts has worked to develop single-chip LIDAR devices, which could eliminate the moving parts in existing devices — such as tiny gimbaled mirrors used to direct the light beams in a scanning pattern — replacing them with fixed, electrically steerable phased-array systems, like those now used for cellphone tower antennas.

“LIDAR systems that exist today are both bulky and expensive, because they use mechanically scanned lasers,” Watts says. But doing the same thing at the nanoscale, using phased-array systems on a chip, could drastically reduce size and cost, providing high-resolution, chip-scale, 3-D imaging capabilities that do not exist today, he says.

There are many other areas where integration of photonics and electronics could lead to big advances, including in biological and chemical sensors that could have greater sensitivity than existing electronic versions, and in new kinds of medical imaging systems, such as optical coherent tomography.

“The goal of this initiative is to lower the barriers to entry in this field for U.S. companies,” Watts says. It is intended to function much like a major public-private initiative that helped pave the way, decades ago, for the development of electronic chip manufacturing in the U.S.

Significant photonic chip manufacturing capabilities have been developed at SUNY Poly, in Albany, New York. That facility has already made the world’s largest silicon-based photonic circuit, a chip designed at MIT, and built using industry-standard 300-millimeter-wide silicon wafers, Watts says.

Contributions in education and training

MIT will also host AIM Photonics’ program in education and workforce development, which Kimerling will direct. This will include developing educational materials — ranging from K-12 through continuing education — to prepare future employees for this emerging industry, including teaching on the design of integrated photonic devices. MIT will also lead workforce development, with an emphasis on including veterans, underrepresented minorities, and other students, by developing a variety of materials to teach about the new technologies.

MIT will work to support internships, apprenticeships, and other forms of hands-on training in a national network of industry and university partners. The effort will also support an industry-wide roadmap to help align the technology supply chain with new manufacturing platforms.

Kimerling says that a significant issue in developing a robust photonics industry is the need to develop a trained workforce of people who are familiar with both electronics and optical technology — two very different fields. Educational programs that encompass these disparate fields “are important, and don’t exist today in one organization,” he says.

One expected impact of the new initiative is the development of a corridor along Interstate 90, from Boston to Rochester, New York, of industrial firms building on the base of new technology to develop related products and services, much as Silicon Valley emerged in California around companies such as Intel and their chip-making technology.

Other major members of AIM Photonics include the University of Arizona, the University of Rochester, and the University of California at Santa Barbara. In addition to the Department of Defense, federal funding for the project will come from the National Science Foundation, the Department of Energy, the National Institute for Standards and Technology, and NASA.

Roots in the Advanced Manufacturing Partnership

Today’s news flows from the work of the Advanced Manufacturing Partnership (AMP), a White House-led effort begun in 2011 with the aim of bringing together industry, universities, and the federal government to identify and invest in key emerging technologies, with the idea of stoking a “renaissance in American manufacturing.”

AMP was inaugurated with former MIT President Susan Hockfield as co-chair; MIT President L. Rafael Reif subsequently served in that same capacity as part of “AMP 2.0.” Those groups’ work led to President Barack Obama’s commitment to establish a National Network of Manufacturing Innovation, to consist of linked institutes such as the one announced today.

“Massachusetts’ strong role in the AIM Photonics team stems from a collaboration involving MIT and many other partner organizations across the Commonwealth: universities, community colleges, and large and small manufacturers throughout the integrated photonics supply chain,” says Krystyn Van Vliet, a professor of materials science and engineering and biological engineering, and MIT faculty lead for AMP 2.0. “The support of Gov. Charlie Baker and Secretary of Housing and Economic Development Jay Ash was key to the success of the AIM Photonics team, and we appreciate their efforts. This manufacturing institute will help Massachusetts inspire and prepare the next generation of integrated photonics manufacturing careers, businesses, and leaders.”

“Today’s announcement is a testament to the outstanding team of industrial and academic leaders assembled by AIM Photonics and its plan to establish the U.S. as a global leader in this emerging technology,” says Michael Liehr, AIM CEO and SUNY Poly executive vice president of innovation and technology and vice president of research. “This would not have been possible without the critical support of Gov. Andrew Cuomo, whose pioneering leadership in establishing New York state’s globally recognized, high-tech R&D ecosystem has enabled historic economic growth and innovation and secured our partnership with the state of Massachusetts. SUNY Poly is excited to be working with partners such as MIT on this initiative, which will be truly transformational for both the industry and the nation.”

Silicon Photonics id39403 Researchers at the University of Rochester have shown that defects on an atomically thin semiconductor can produce light-emitting quantum dots. The quantum dots serve as a source of single photons and could be useful for the integration of quantum photonics with solid-state electronics — a combination known as integrated photonics.

Scientists have become interested in integrated solid-state devices for quantum information processing uses. Quantum dots in atomically thin semiconductors could not only provide a framework to explore the fundamental physics of how they interact, but also enable nanophotonics applications, the researchers say.

Quantum dots are often referred to as artificial atoms. They are artificially engineered or naturally occurring defects in solids that are being studied for a wide range of applications. Nick Vamivakas, assistant professor of optics at the University of Rochester and senior author on the paper, adds that atomically thin, 2D materials, such as graphene, have also generated interest among scientists who want to explore their potential for optoelectronics. However, until now, optically active quantum dots have not been observed in 2D materials.

In a paper published in Nature Nanotechnology this week, the Rochester researchers show how tungsten diselenide (WSe2) can be fashioned into an atomically thin semiconductor that serves as a platform for solid-state quantum dots. Perhaps most importantly the defects that create the dots do not inhibit the electrical or optical performance of the semiconductor and they can be controlled by applying electric and magnetic fields.

Vamivakas explains that the brightness of the quantum dot emission can be controlled by applying the voltage. He adds that the next step is to use voltage to “tune the color” of the emitted photons, which can make it possible to integrate these quantum dots with nanophotonic devices.

A key advantage is how much easier it is to create quantum dots in atomically thin tungsten diselenide compared to producing quantum dots in more traditional materials like indium arsenide.

“We start with a black crystal and then we peel layers of it off until we have an extremely thin later left, an atomically thin sheet of tungsten diselenide,” said Vamivakas.1-nano devices howtomakemob

The researchers take two of these atomically thin sheets and lay one over the other one. At the point where they overlap, a quantum dot is created. The overlap creates a defect in the otherwise smooth 2D sheet of semiconductor material. The extremely thin semiconductors are much easier to integrate with other electronics.

The quantum dots in tungsten diselenide also possess an intrinsic quantum degree of freedom — the electron spin. This is a desirable property as the spin can both act as a store of quantum information as well as provide a probe of the local quantum dot environment.

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“What makes tungsten diselenide extremely versatile is that the color of the single photons emitted by the quantum dots is correlated with the quantum dot spin,” said first author Chitraleema Chakraborty. Chakraborty added that the ease with which the spins and photons interact with one another should make these systems ideal for quantum information applications as well as nanoscale metrology.

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The above story is based on materials provided by University of Rochester. Note: Materials may be edited for content and length.

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